SO4^2- is in M
H2S is in M
CH4 is in M
CO2 is in M
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AOM is a rate (mol Ed * L^-1 * y^-1), Ed = electron donor, here CH4)
AOM = fT*vmax*FK*FT
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fT is the temperature contribution. Dimension less.
f(T) = Q10^((T-Ref. T)/10)
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vmax is the maximum turnover rate of SO4^2- and CH4. The unit is mmol Ed * L^-1 * y^-1.
vmax = µ*B/Y*ϕ , at 5 deg C
µ: Max. specific growth rate pr year. Average
from Dale et al 2006 (tab. 4).
B: The steady-state biomass conc. (mol C biomass
L^-1). Calculated from Kallmayer et al 2012 and cell abundance data from
M5.
Y: Yield (mol C biomass produced per
mol E(D) consumed). Calculated from Dale et al 2006 (tab. 4).
ϕ: Porosity
av. of the SMTZ from M5 data.
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FK is the kinetic contribution and is unitless.
FK = ([Ed]/KEd + [Ed]) ([Ea]/KEa+[Ea])
[Ed]: Conc. of e- donor.
KEd: half-saturation constant of e- donor.
[Ea]: Conc. of e- acceptor.
KEa: half-saturation constant of e- acceptor.
All in M.
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FT is the thermodynamic contribution and is unitless.
FT = 1 - exp (ΔGNET/chi*R*T)
ΔGNET is the net Gibbs energy change from the reaction.
ΔGNET = ΔGINSITU + ΔGBQ
ΔGINSITU = -16.9+8.3145*[T]*Ln([HS^-]*[HCO3^-]/[SO4^2-]*[CH4])
ΔGBQ = 1.75 avraged from Dale et al 2008.